Product ID:TERT-BUTANOL B2138
MSDS Date:01/01/1999
FSC:6810
NIIN:00N093218
Status Code:A
MSDS Number: CJWLJ

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

TERT-BUTANOL

CAS: 75-65-0

RTECS: EO1925000

OSHA PEL 300 MG/M3;100 PPM

ACGIH TLV: 303 MG/M3;100 PPM

LD50 LC50 Mixture:LD50: (ORAL,RAT) 3500 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: HARMFUL IF INHALED. MAY
BE HARMFUL IF SWALLOWED. MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
CAUSES SEVERE EYE IRRITATION. CAUSE SKIN IRRITATION. MATERIAL IS
IRRITATING TO MUCOUS MEMBRANES & UPPER REPIRATORY TRACT. CAN CAUSE
CNS DEPRESSION. EXPOSURE CAN CAUSE: GASTROINTESTINAL DISTURBANCES.
CHRONIC EFFECTS: MAY CAUSE REPRODUCTIVE DISORDERS. TARGET ORGAN(S):
CENTRAL NERVOUS SYSTEM, LIVE R, KIDNEYS, BLOOD.
Explanation of Carcinogenicity:THIS PRODUCT IS OR CONTAINS A COMPONENT
THAT IS NOT CLASSIFICABLE AS TO ITS CARCINOGENICITY BASED ON ITS
IARC, ACGIH, NTP OR EPA CLASSIFICATION.
Effects of Overexposure:SEE HEALTH HAZARDS. OTHER PRECAUTIONS: EPA
TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998. NIOSH
ANALYTICAL METHOD, 1994: ALCOHOLS I, 1400. NTP CARCINOGENSIS
STUDIES (DRINKING WATER ); SOME EVI DENCE:MOUSE, RAT NTPTR*
NTP-TR-436,95. NTP CARCINOGENESIS STUDIES; TEST COMPLETED (CAMERA
COPY IN PROGRESS), OCTOBER 1997.

First Aid:IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND
COPIOUS AMOUNTS OF WATER. IN CASE OF CONTACT, IMMEDIATELY FLUSH
EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IF
INHALED, REMOVE T O FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED,
WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A
PHYSICIAN.

Flash Point:=11.7C, 53.F
Autoignition Temp:=480.C, 896.F
Lower Limits:2.4%
Upper Limits:8.0%
Extinguishing Media:EXTREMELY FLAMMABLE. CARBON DIOXIDE, DRY CHEMICAL
POWDER OR APPROPRIATE FOAM. WATER MAY BE EFTIVE FOR COOLING, BUT
MAY NOT EFFECT EXTINGUISHMENT.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IGNITION AND FLASH BACK. CONTAINER EXPLOSION MAY OCCUR
UNDER FIRE CONDITIONS.

Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF
IGNITION. WEAR NIOSH APPRVD SELF-CONTAINED BREATHING APPARATUS,
RUBBER BOOTS AND HEAVY RUBBER GLOVES. COVER WITH AN ACTIVATED
CARBON ABSORBENT, TAKE UP & PLACE I N CLOSED CONTAINERS. TRANSPORT
OUTDOORS. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP
IS COMPLETE.

Handling and Storage Precautions:DO NOT BREATHE VAPOR. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. KEEP TIGHTLY CLOSED. KEEP AWAY FROM
HEAT, SPARKS, AND OPEN FLAME. STORE IN COOL DRY PLACE.
Other Precautions:SARA TITLE III: NOHS 1974: HZD 14400; NIS 11; TNF
820; NOS 25; TNE 3121. NOES 1983: HZD 14400; NIS 128; TNF 10682;
NOS 84; TNE 171420; TFE 26045. EPA GENETOX PROGRAM 1988, NEG: N
CRASSA-REVERSION. EPA TSCA SECTION 8(B) CHEM INVENTORY. EPA TSCA
SECTION 8(D) UNPUBLISHED HLTH/SFTY STUDIES. (EFTS OF OVE REXP)

Respiratory Protection:WEAR APPROPRIATE NIOSH-APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health

Boiling Pt:=83.C, 181.4F
Melt/Freeze Pt:>25.C, 77.F
M.P/F.P Text:25 C TO 26 C
Vapor Pres:31@ 20C. 44 @ 26C
Vapor Density:2.5
Spec Gravity:0.775
Appearance and Odor:WHITE SOLID.

Stability Indicator/Materials to Avoid:YES
ACIDS, ACID CHLORIDES, ACID ANHYDRIDES, OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.

Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGUL ATIONS.

Toxicological Information:SEE HEALTH HAZARDS. RTECS #: EO1925000.
TERT-BUTYL ALCOHOL. TOX DATA: ORL-RAT LD50:3500 MG/KG SCIEAS
116,663,1952. IPR-MUS LD50:399 MG/KG RCOCB8 26,75,1979. IVN-MUS
LD50:1538 MG/KG AIPTAK 135,330,1962 . ORL-RBT LD50:3559 MG/KG
IMSUAI 41,31,1972. TARGET ORGAN DATA: LIVER (OTHER CHANGES).
EFFECTS ON EMBRYO OR FETUS (FETOTOXICITY). ONLY SELECTED REGISTRY
OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED
HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS. OTHER INFO: OEL-SWEDEN:TWA 50 PPM (150
MG/M3);STEL 75 PPM (250 MG/M3);SKIN JAN 1993. OEL-SWITZERLAND:TWA
100 PPM (300 MG/M3);STEL200 PPM (600 MG/M3) JAN 1993.
OEL-TURKEY:TWA 100 PPM (300 MG/M3) JAN 1993. OEL-UNITED KINGDOM:TWA
100 PPM (300 MG/M3);STEL 150 PPM JAN 1993. OELIN BULGARIA,
COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV. OEL I N NEW ZEALAND,
SINGAPORE, VIETNAM CHECK ACGIH TLV. NIOSH REL TO T-BUTYL
ALCOHOL-AIR:10H TWA 100 PPM;STEL 150PPM NIOSH* DHHS #92-100,1992.
(OTHER PREC)
Federal Regulatory Information:EUROPEAN INFO: EC INDEX NO:
603-005-00-1. HIGHLY FLAMMABLE. TOXIC R 11 HIGHLY FLAMMABLE. R 20
HARMFUL BY INHAL. S 9 KEEP CNTNR IN WELL-VENTILATED PLACE. S 16
KEEP AWAY FROM SOURCES OF IGNIT - NO SMKNG . REVIEWS, STDS, & REGS.
OEL=MAK. ACGIHTLV-NOT CLASSIFIABLE AS HUMAN CARCIN DTLVS* TLV/BEI,
1997. ACGIH TLV-TWA 303 MG/M3 (100 PPM) DTVS# TLV/BEI, 1997. EPA
FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATIO N OR RE-REGISTRATION
FEREAC 54,7740,1989. MSHA STD-AIR:TWA 100 PPM (300 MG/M3) DTLVS*
3,32,1971. OSH A PEL (GEN INDU):8H TWA 100 PPM (300 MG/M3) CFRGBR
29,1910.1000,1994. (STATE REGULATORY INFO)
State Regulatory Information:N/P. FED REGULATORY INFO: OSHA PEL
(CONSTRUC):8H TWA 100 PPM (300 MG/M3) CFRGBR 29,1926.55,1994. OSHA
PEL (SHIPYARD):8H TWA 100 PPM (300 MG/M3) CFRGBR 29,1915.1000,1993.
OSHA PEL (FED CONT) :8H TWA 10 0 PPM (300 MG/M3) CFRGBR
41,50-204.50,1994. OEL-AUSTRALIA:TWA 100 PPM (300 MG/M3);STEL 150
PPM (450 MG/M3) JAN 1993. OEL-AUSTRIA:TWA 100 PPM (300 MG/M3) JAN
1993. OEL-BELGIUM:TWA 100 PPM (303 MG/M3); STEL 150 PPM (455
MG/M3) JAN 1993. OEL-DENMARK:TWA 50 PPM (150 MG/M3);SKIN JAN 1993.
OEL-FRANCE:TWA 100 PPM (300 MG/M3) JAN 1993. OEL-GERMANY:TWA 100
PPM (300 MG/M3) JAN 1993. (OTHER INFO)